Sulfide Solid Electrolyte Argyrodite Type Li6PS5Cl
Product information "Sulfide Solid Electrolyte Argyrodite Type Li6PS5Cl"
Research Material Argyrodit Solid Electrolyte Manufactured by Ampcera
Manufacturer: Ampcera Inc. (Ampcera Inside™)
"Ampcera holds a growing IP portfolio of high-performance, engineered solid electrolyte materials, revolutionary scalable manufacturing processes, and novel designs for solid-state batteries (SSBs) used in electric vehicles (EVs) and beyond."
Standard Quantity: 10 g
Product Number: PO0200
Nominal Composition: Li6PS5Cl (LPSCl) Theoretical Density: 1.64 g/cm3
Material Type: Argyrodit, Li-Argyrodite Crystal Phase, Lithium Phosphorus Sulfur Chloride (LPSCl)
Purity: synthesized from >99.9% precursor materials
Product Form: light yellow powder Particle Size: D50 5 mS/cm at R.T.
Electronic Conductivity: ~10-8 S/cm at room temperature (25 °C)
Wide Electrochemical Stability Window: from 0 to 7 V vs. Lithium (Ref. S. Boulineau, et al., Solid State Ionics, 221 (2012) P1-5.)
Shipping and Handling: This material is classified as hazardous goods and requires special packaging and shipment to comply with regulatory requirements. Hazardous goods shipping applies to this product.
Applications: Solid electrolyte material for all solid-state lithium-ion batteries. Cathode electrolyte (Catholyte).
Storage and Precautions: Sensitive to water. Store and handle in a dry environment. Note: Process optimization may be required for best performance in your specific application.
Material as Research Supply for Future Lithium Solid-State Batteries
About the Argyrodit Solid Electrolyte: Argyrodit, Li6PS5X (X = Cl, Br), are considered among the most promising solid electrolytes for solid-state batteries. Argyrodit-type crystal materials such as Li6PS5Cl are promising solid electrolytes for all-solid-state lithium-ion batteries due to their high ionic conductivity (up to > 3 mS/cm at room temperature), good processability, and excellent electrochemical stability (> 7V vs. Lithium). With its proprietary technology, Ampcera Inc. is the world's first company to successfully commercialize the argyrodite-type Li6PS5Cl solid electrolyte, with a production capacity exceeding one metric ton per year. Custom processing is also available to meet customer-specific technical requirements.
Research Publications on Li6PS5Cl
- Sylvain Boulineau, Matthieu Courty, Jean-Marie Tarascon, Virginie Viallet, Mechanochemical synthesis of Li-argyrodite Li6PS5X (X = Cl, Br, I) as sulfur-based solid electrolytes for all solid state batteries application, Solid State Ionics, Volume 221, 3 August 2012, Pages 1-5 https://doi.org/10.1016/j.ssi.2012.06.008
- Interface Stability of Argyrodite Li6PS5Cl toward LiCoO2, LiNi1/3Co1/3Mn1/3O2, and LiMn2O4 in Bulk All-Solid-State Batteries
Jérémie Auvergniot, Alice Cassel, Jean-Bernard Ledeuil, Virginie Viallet, Vincent Seznec, and Rémi Dedryvère, Chemistry of Materials 2017 29 (9), 3883-3890, DOI: 10.1021/acs.chemmater.6b04990 - Zhi Deng, Yifei Mo and Shyue Ping Ong, Computational studies of solid-state alkali conduction in rechargeable alkali-ion batteries, NPG Asia Materials (2016) 8, e254; doi:10.1038/am.2016.7
- Yu, C., Ganapathy, S., Hageman, J., van Eijck, L., van Eck, E., Zhang, L., Wagemaker, M. (2018). Facile Synthesis toward the Optimal Structure-Conductivity Characteristics of the Argyrodite Li6PS5Cl Solid-State Electrolyte. ACS applied materials & interfaces, 10(39), 3329633306. doi:10.1021/acsami.8b07476
- Yuki Kato et al. High-power all-solid-state batteries using sulfide superionic conductors, Nature Energy (2016). download pdf from the above link
- R. P. Rao, S. Adams, Studies of lithium argyrodite solid electrolytes for all‐solid‐state batteries, physica status solidi (a) – applications and materials science, Volume 208, Issue 8, August 2011, Pages 1804-1807
- Heng Wang, Chuang Yu, Swapna Ganapathy, Ernst R.H. van Eck, Lambert van Eijck and Marnix Wagemaker, A lithium argyrodite Li6PS5Cl0.5Br0.5 electrolyte with improved bulk and interfacial conductivity, Journal of Power Sources, 10.1016/j.jpowsour.2018.11.029, 412, (29-36), (2019).
- Qing Zhang, Daxian Cao, Yi Ma, Avi Natan, Peter Aurora and Hongli Zhu, Sulfide‐Based Solid‐State Electrolytes: Synthesis, Stability, and Potential for All‐Solid‐State Batteries, Advanced Materials, 31, 44, (2019).
- Parvin Adeli, J. David Bazak, Kern Ho Park, Ivan Kochetkov, Ashfia Huq, Gillian R. Goward and Linda F. Nazar, Boosting Solid‐State Diffusivity and Conductivity in Lithium Superionic Argyrodites by Halide Substitution, Angewandte Chemie, 131, 26, (8773-8778), (2019).
- Schlenker, Ruth, Hansen, Anna-Lena, Senyshyn, Anatoliy, Zinkevich, Tat Michael Knapp, Tatiana, Hupfer, Thomas, Ehrenberg, Helmut, and Indris, Sylvio (2020): Structure and Diffusion Pathways in Li6PS5Cl Argyrodite from Neutron Diffraction, Pair-Distribution Function Analysis, and NMR, Chemistry of Materials (2020), 32, 19, 8420–8430, https://bib-pubdb1.desy.de/record/452838/files/document%28102%29.pdf
Technical Details
| Operating Conditions: | chemical resistant, cleanroom suitable |
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